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2017 WAEC GCE Chemistry Alternative to Practical Answers

Original Neco 2018 Timetable for the June / July Examination / WAEC May / June 2018 / 2019 Result is Out – See How to Check Yours / A Story that Ends With The Saying: Strike while the iron is hot /

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2017 WAEC GCE Chemistry Alternative to Practical Answers by : 8:02 am On September 15, 2017

2017 WAEC GCE Chemistry Alternative to Practical Answers

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(1ai)
Burette Reading(cm^3)| 1 | 2 | 3 |
Final Reading |33.10|30.00|25.00|
Initial Reading | 9.60|7.50 |2.40 |
Volume of F used (cm^3)|23.50|22.50|22.60.

(1aii)
Average volume of F used
=22.50 + 22.60 / 2
=22.55cm^3

(1bi)
GIVEN:Molar Conc of Kmn04 =0.200mol/dm^2
Volume of Kmn04 used =22.55cm^3
Molar Conc of FeSo4. 7H2O=?
Volume of FeSO4.7H2O=25cm^3
Mole ratio of Kmn04 =1
Mole ratio of FeSO4.7H2O=5

Using,
Molar Conc of KeSO4.7H2O x Volume(FeSo4.7H2O) =n(FeSO4.7H2O)/n(KmnO4)

=molar Conc x 25 / 0.0200 x 22.55 = 5/1

=Molar Conc. x 25=0.0200 x 22.55 x 5
=Molar Conc =0.0200 x 22.55 x 5 / 25

=Molar Conc =0.0902mol/dm^3
Hence, Concentration of FeSo4.7H2O in E = 0.0902mol/dm^3
(1ci)
Hydrochloric acid(HCL) is a mild reducing agent and so it will consume a certain amount of Kmn04 during titration. This will give a slightly higher value of Kmn04 consumption than the actual amount needed by the analyte

(1cii)
As Kmn04 is a Dees purple colour, it is not possible to take readings from the button of the meniscus on the burette as in usual. Hence, the top, of the meniscus is used(visibility consideration)

(1ciii)
No indicator is used because Kmn04 serves as an indicator

2a)
TEST|OBSERVATION|INFERENCE
2ai)
TEST:A+distilled water and stirred
OBSERVATION:All of A dissolved to form uniform mixture
INFERENCE:A is soluble in salt
2aii)
TEST:A(aq)+litmus paper
OBSERVATION:Turns blue litmus paper red
INFERENCE:A is an acidiic salt
2aiii)
TEST:A(aq)+NaOH(aq)- in drops,
- then in excess
OBSERVATION:-White gelatinous precicpitate,
-Precipitate soluble,dissolved
INFERENCE:-Pb^2+ or Zn^2+ present
-Al^3+ present
2aiv)
TEST:A(aq)+NH3(aq)- in dropss,
-In excess
OBSERVATION:-White gelatinous precipitate
-Precipitate insoluble
INFERENCE:-Pb^2+ or Zn^2+ or Al^3+
-Al^3+ present
2av)
TEST:A(aq)+FeSO4(aq)+conc H2SO4
OBSERVATION:Brown ring forms between the two solutions
INFERENCE:NO3^- confirmed
2bi)
A is aluminium trioxonitrate(v)
2bii)
Al(NO3)3
2c)
TEST|OBSERVATION|INFERENCE
2ci)
TEST:K+NaHCO3(aq)
OBSERVATION:No visible reaction is observed
INFERENCE:NaHCO3(aq) does not show result for alkanols(K)
2cii)
TEST:K+benedict solution+heat
OBSERVATION:There is no change in the colour of the benedicts solution
INFERENCE:Benedicts solution is not an indicator for alkanols(K)
2ciii)
TEST:K+KMnO4(aq)
OBSERVATION:KMnO4(aq) solution changes from purple to colourless
INFERENCE:Alkanol is being oxidized by KMnO4
2civ)
TEST:K+CH3COOH+conc H2SO4
OBSERVATION:pleasant fruity smell is observed
INFERENCE:Esterification reaction has occured

3a)
-Putsome distilled water in a beaker
-Measure 100cm^3 of 2.00mol/dm^3 of the stock solution by means of a burette and pour all the solution into the beaker containing the distilled water
-Stir the solution
-Transfer the solution into a 250cm^3 volumetric flask by means of a funnel
-Ensure that all the solution in the volumetric flask has been transferred by thoroughly rinsing the inside of the beaker with distilled water
-Dilute the solution in the volumetric flask with distilled water until it reaches the 250cm^3 mark
-Shake the solution carefully
3b)
-CH3COONa:It forms basic solution
-Al2(SO4)3:Acidic solution
-KNO3:Neutral solution
3c)
Acidified potasium tetraoxomanganate(vii) KMnO4 was placed in the burette

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Original Neco 2018 Timetable for the June / July Examination / WAEC May / June 2018 / 2019 Result is Out – See How to Check Yours / A Story that Ends With The Saying: Strike while the iron is hot /

 

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